First up, a little tv show that I keep rooting for but still hasn't found its own - Private Practice. Dr. Addison Forbes Montgomery is one hot doctor, and rocks her super chic style regardless of the circumstances.
Check her out here in a classic trench and gold brocade skirt while she helps a call girl whose Tom beat the crap out of her. Not even dealing with hookers can keep her from strutting her super style.

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Banana Republic, Sale $69.99

Jessica Simpson, Sale $105.90
This look is a great everyday business casual outfit. Not the sexiest thing she's worn on the show, but, hey, you shouldn't be dressing sexy to work anyway.

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Banana Republic, $59

Ann Taylor, $34

Esprit, Sale $59.70
Sometimes the other doctors get in on the well dressed action. Here's Naomi in a classic black sheath dress for work contemplating helping a cancer victim get pregnant, but the cancer victim is a patient at the rival practice! *GASP*

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Diane von Furstenberg, $365
And Addison put on her serious ruffle neck top to tell the other doctors they need to turn their practice around.

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Geren Ford, Sale $120

J. Crew, $98

Forever 21, $6.80
We will ignore the unfortunate hairstyle and focus on the funly printed dress Addison wore to tell the man with a secret wife that his non-secret wife was pregnant.

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Diane von Furstenberg, Sale $219
Forever 21